In the attached optimized QM7-X geometry for molecule 7040 (16 atoms), row 3 is the molecule's only sulfur atom, and rows 4 and 5 are the two oxygen atoms with the shortest measured distance to row 3. What is the angle at row 3, measured from row 4 to row 3 to row 5? Report the value in degrees to two decimal places.

The attachment is one complete optimized XYZ structure, 16 atoms, coordinates in angstrom. Atom rows are numbered starting at 1, immediately after the two header lines. Do not renumber or reorder atoms; use the row numbers exactly as given.