OE62 molecules EZUTAU (66 atoms) and ZOGVEW (79 atoms) are two independent real molecules, both with their own maximum pairwise atom distance in [1,10) nm. Using each molecule's attached geometry and official PBE+vdW(vacuum) orbital-energy lists, compute the HOMO-LUMO gap of each. Report both gaps in eV to four decimal places, state which is larger, and explain whether comparing just these two molecules establishes a general relationship between molecular size and gap.

The attachments are the EZUTAU XYZ geometry (S0012, 66 atoms) and the ZOGVEW XYZ geometry (S0014, 79 atoms). Coordinates are in angstrom (1 nm = 10 angstrom). Atom rows are numbered starting at 1, immediately after the two header lines. Do not renumber or reorder atoms; use the row numbers exactly as given. This is a single relaxed molecular geometry, not a periodic cell: apply no periodic images or symmetry expansion. Occupied orbital energies are listed in ascending order; the HOMO is the last (highest) value in the occupied list. Unoccupied orbital energies are also listed in ascending order; the LUMO is the first (lowest) value in the unoccupied list. The HOMO-LUMO gap is LUMO minus HOMO, in eV. Only virtual levels below the vacuum level are listed for the unoccupied set.

EZUTAU PBE+vdW(vacuum) occupied energies (eV): -5.42644 is the HOMO (last value). EZUTAU PBE+vdW(vacuum) unoccupied energies (eV): -1.16051 is the LUMO (first value). ZOGVEW PBE+vdW(vacuum) occupied energies (eV): -4.43374 is the HOMO (last value). ZOGVEW PBE+vdW(vacuum) unoccupied energies (eV): -2.11882 is the LUMO (first value).