For OE62 molecule GALPAL, using the attached geometry and the official PBE+vdW(vacuum) occupied/unoccupied orbital-energy lists, identify the HOMO and LUMO and compute the HOMO-LUMO gap. Report all three values in eV to four decimal places.

The attachment is the GALPAL XYZ geometry (S0008), 41 atoms. Coordinates are in angstrom (1 nm = 10 angstrom). Atom rows are numbered starting at 1, immediately after the two header lines. Do not renumber or reorder atoms; use the row numbers exactly as given. This is a single relaxed molecular geometry, not a periodic cell: apply no periodic images or symmetry expansion. Occupied orbital energies are listed in ascending order; the HOMO is the last (highest) value in the occupied list. Unoccupied orbital energies are also listed in ascending order; the LUMO is the first (lowest) value in the unoccupied list. The HOMO-LUMO gap is LUMO minus HOMO, in eV. Only virtual levels below the vacuum level are listed for the unoccupied set.

PBE+vdW(vacuum) occupied energies (eV): HOMO (last value of the full list) = -5.61075. PBE+vdW(vacuum) unoccupied energies (eV): LUMO (first value of the full list) = -1.63809.