Using d(110)=1.1900819259 nm for ZIF-8 (from the preceding plane-spacing calculation) and a CuKa X-ray wavelength of 0.15406 nm, apply Bragg's law 2*d*sin(theta)=n*lambda (n=1) to find the first-order diffraction angle 2*theta. Report the value in degrees to two decimal places. Is this angle larger or smaller than you would get from a typical small-unit-cell inorganic salt (a a1-2 angstrom scale reflection)? Explain why in one sentence referencing the cell size.

This is a pure calculation from the stated d-spacing and wavelength; no coordinate file is needed beyond the ZIF-8 structural context already established (S0002 attached for that context). Use n=1 (first order) and the exact stated wavelength.