In the indicated WP6 carboxylate arm, does this supplied geometry encode nearly equivalent C-O distances or clearly different ones? Calculate both C20-O22 and C20-O24 lengths to three decimal places, then explain which qualitative bonding description this pattern is consistent with and one limitation of drawing an electronic conclusion from these model coordinates.

Use the supplied complete 150-atom WP6 XYZ attachment (asset S0005). Coordinates are in angstrom. Atom rows are numbered from 1 after the two header lines; a physical file line number is atom row + 2. Use this one supplied conformer without relaxation. Labels C1, C3, etc. below mean element plus XYZ atom row, not unique original PDB atom names. Focus only on the modeled deprotonated arm centered at carbon C20 (row 20), bonded to oxygens O22 and O24 (rows 22 and 24) and arm carbon C14. For this question, call the two lengths nearly equivalent when their absolute difference is at most 0.01 angstrom. This is an operational comparison tolerance, not an experimental uncertainty. Discuss only consistency of this local geometry with a bonding description; do not predict pKa, binding affinity, or solution protonation.

Attachment: WP6.xyz
150
Coordinates in angstrom; atoms numbered from 1.
C 5.066 1.219 -1.643
C 5.319 -1.213 -0.267
C 4.798 0.033 -2.350
C 5.199 1.187 -0.231
C 5.320 -0.026 0.489
C 4.941 -1.181 -1.634
H 5.280 2.123 0.320
H 4.821 -2.116 -2.178
C 4.530 0.003 -3.858
H 5.073 -0.854 -4.279
H 5.032 0.860 -4.328
O 5.266 2.377 -2.381
O 5.769 -2.370 0.352
C 6.340 3.215 -1.875
H 7.111 2.615 -1.372
H 5.913 3.923 -1.155
C 6.593 -3.209 -0.504
H 5.937 -3.916 -1.024
H 7.134 -2.609 -1.248
C 7.064 4.004 -3.001
C 7.670 -3.998 0.291
O 7.958 3.382 -3.659
O 8.739 -3.376 0.588
O 6.801 5.247 -3.085
O 7.454 -5.241 0.463
C 1.110 1.219 -5.209
C 2.428 -1.213 -4.740
C 0.364 0.033 -5.330
C 2.400 1.187 -4.618
C 3.083 -0.027 -4.362
C 1.055 -1.181 -5.096
H 2.918 2.122 -4.413
H 0.524 -2.116 -5.264
C -1.076 0.003 -5.852
H -1.169 -0.854 -6.533
H -1.232 0.860 -6.521
O 0.571 2.377 -5.751
O 3.189 -2.371 -4.820
C 1.547 3.215 -6.428
H 2.367 2.615 -6.844
H 1.956 3.922 -5.699
C 2.860 -3.209 -5.961
H 2.081 -3.916 -5.654
H 2.486 -2.609 -6.802
C 0.934 4.004 -7.618
C 4.086 -3.999 -6.497
O 0.729 5.247 -7.433
O 4.127 -5.241 -6.223
O 0.811 3.382 -8.721
O 4.878 -3.376 -7.274
C -3.956 1.220 -3.566
C -2.891 -1.213 -4.473
C -4.434 0.033 -2.980
C -2.799 1.188 -4.387
C -2.236 -0.026 -4.851
C -3.886 -1.181 -3.462
H -2.363 2.123 -4.733
H -4.297 -2.116 -3.086
C -5.606 0.003 -1.994
H -6.242 -0.853 -2.254
H -6.264 0.860 -2.194
O -4.695 2.377 -3.370
O -2.580 -2.370 -5.172
C -4.794 3.215 -4.553
H -4.744 2.615 -5.472
H -3.957 3.923 -4.543
C -3.733 -3.209 -5.457
H -3.856 -3.916 -4.629
H -4.648 -2.609 -5.554
C -6.130 4.005 -4.617
C -3.584 -3.998 -6.787
O -6.072 5.248 -4.347
O -3.326 -5.241 -6.687
O -7.147 3.383 -5.063
O -3.861 -3.376 -7.862
C -5.066 1.219 1.643
C -5.319 -1.213 0.267
C -4.798 0.033 2.350
C -5.199 1.187 0.231
C -5.320 -0.026 -0.489
C -4.941 -1.181 1.634
H -5.280 2.123 -0.320
H -4.821 -2.116 2.178
C -4.530 0.003 3.858
H -5.073 -0.854 4.279
H -5.032 0.860 4.328
O -5.266 2.377 2.381
O -5.769 -2.370 -0.352
C -6.340 3.215 1.875
H -7.111 2.615 1.372
H -5.913 3.923 1.155
C -6.593 -3.209 0.504
H -5.937 -3.916 1.024
H -7.134 -2.609 1.248
C -7.064 4.004 3.001
C -7.670 -3.998 -0.291
O -6.801 5.247 3.085
O -7.454 -5.241 -0.463
O -7.958 3.382 3.659
O -8.739 -3.376 -0.588
C -1.110 1.219 5.209
C -2.428 -1.213 4.740
C -0.364 0.033 5.330
C -2.400 1.187 4.618
C -3.083 -0.027 4.362
C -1.055 -1.181 5.096
H -2.918 2.122 4.413
H -0.524 -2.116 5.264
C 1.076 0.003 5.852
H 1.169 -0.854 6.533
H 1.232 0.860 6.521
O -0.571 2.377 5.751
O -3.189 -2.371 4.820
C -1.547 3.215 6.428
H -2.367 2.615 6.844
H -1.956 3.922 5.699
C -2.860 -3.209 5.961
H -2.081 -3.916 5.654
H -2.486 -2.609 6.802
C -0.934 4.004 7.618
C -4.086 -3.999 6.497
O -0.729 5.247 7.433
O -4.127 -5.241 6.223
O -0.811 3.382 8.721
O -4.878 -3.376 7.274
C 3.956 1.220 3.566
C 2.891 -1.213 4.473
C 4.434 0.033 2.980
C 2.799 1.188 4.387
C 2.236 -0.026 4.851
C 3.886 -1.181 3.462
H 2.363 2.123 4.733
H 4.297 -2.116 3.086
C 5.606 0.003 1.994
H 6.242 -0.853 2.254
H 6.264 0.860 2.194
O 4.695 2.377 3.370
O 2.580 -2.370 5.172
C 4.794 3.215 4.553
H 4.744 2.615 5.472
H 3.957 3.923 4.543
C 3.733 -3.209 5.457
H 3.856 -3.916 4.629
H 4.648 -2.609 5.554
C 6.130 4.005 4.617
C 3.584 -3.998 6.787
O 6.072 5.248 4.347
O 3.326 -5.241 6.687
O 7.147 3.383 5.063
O 3.861 -3.376 7.862